You can scan for block devices that may be used as physical volumes with the lvmdiskscan command, as shown in the following example.

# lvmdiskscan
/dev/ram0                    [       16.00 MB]
  /dev/sda                     [       17.15 GB]
  /dev/root                    [       13.69 GB]
  /dev/ram                     [       16.00 MB]
  /dev/sda1                    [       17.14 GB] LVM physical volume
  /dev/VolGroup00/LogVol01     [      512.00 MB]
  /dev/ram2                    [       16.00 MB]
  /dev/new_vg/lvol0            [       52.00 MB]
  /dev/ram3                    [       16.00 MB]
  /dev/pkl_new_vg/sparkie_lv   [        7.14 GB]
  /dev/ram4                    [       16.00 MB]
  /dev/ram5                    [       16.00 MB]
  /dev/ram6                    [       16.00 MB]
  /dev/ram7                    [       16.00 MB]
  /dev/ram8                    [       16.00 MB]
  /dev/ram9                    [       16.00 MB]
  /dev/ram10                   [       16.00 MB]
  /dev/ram11                   [       16.00 MB]
  /dev/ram12                   [       16.00 MB]
  /dev/ram13                   [       16.00 MB]
  /dev/ram14                   [       16.00 MB]
  /dev/ram15                   [       16.00 MB]
  /dev/sdb                     [       17.15 GB]
  /dev/sdb1                    [       17.14 GB] LVM physical volume
  /dev/sdc                     [       17.15 GB]
  /dev/sdc1                    [       17.14 GB] LVM physical volume
  /dev/sdd                     [       17.15 GB]
  /dev/sdd1                    [       17.14 GB] LVM physical volume
  7 disks
  17 partitions
  0 LVM physical volume whole disks
  4 LVM physical volumes